Emma Peel on the series The Avengers, which made her an instant celebrity in both Britain and the United States. Though she wasn’t offered many starring roles in movies over the course of her long career, one of them made history: In the James Bond film On Her Majesty’s Secret Service, Rigg played the only woman to marry the elusive international spy throughout the six-decade franchise. Spoiler alert: She was killed off before the Pikolo I’m Pickle-o Rick shirt final credits rolled. Younger American audiences might know Rigg best from her role as Lady Olenna Tyrell on Game of Thrones, for which she was nominated for four Emmy Awards. Those weren’t Rigg’s only Emmy nominations, though; she collected nine total during her career, along with one best-supporting-actress win for her role as Mrs. Danvers in a miniseries production of Rebecca. In Rigg won a best-actress award for her role in Mother Love.